Fundamental Study of Carbon Materials Derived from Empty Fruit Bunch via Hydrothermal Carbonization

Kanogpan GUNTAGERNG, Gasidit PANOMSUWAN, Apiluck EIAD-UA

Abstract


The utilization of biomass has recently gained great attention in recent years owing to growth of global environmental concerns. The aim of this work is to study the morphology of carbon materials derived from biomass oil palm empty fruit bunch (EFB) via hydrothermal carbonization (HTC) at different temperatures (160 - 200 °C) and times (4 - 12 h) followed by carbonization at 300 - 900 °C under nitrogen atmosphere for 2 h. The physiochemical properties of carbon sample were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and surface area analysis. The results demonstrated that the increase of hydrothermal temperature, hydrothermal time, and carbonization temperature resulted in the formation of carbon materials with higher surface area, porosity and carbon content. Our results revealed that carbon derived from EFB via HTC at optimal condition exhibited porous structure with high surface area, which can be further applied for absorbent applications.

Keywords


Biomass, empty fruit bunch, hydrochar, hydrothermal carbonization

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References


D Kalderis, MS Kotti, A Méndez and G Gasco. Characterization of hydrochars produced by hydrothermal carbonization of rice husk. Solid Earth 2014; 5, 477-83.

M Toufiq Reza, J Mumme and A Ebert. Characterization of hydrochar obtained from hydrothermal carbonization of wheat straw digestate. Biomass Convers. Biorefin. 2015; 5, 425-32.

MT Reza, X Yang, CJ Coronella, H Lin, U Hathwaik, D Shintani, BP Neupane and GC Miller. Hydrothermal carbonization (HTC) and pelletization of two arid land plants bagasse for energy densification. ACS Sustain. Chem. Eng. 2016; 4, 1106-14.

HS Kambo and A Dutta. A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications. Renew. Sustain. Energ. Rev. 2015; 45, 359-78.

HPS Abdul Khalil, MS Alwani, R Ridzuan, H Kamarudin and A Khairul. Chemical composition, morphological characteristics, and cell wall structure of Malaysian oil palm fibers. Polym. Plast. Tech. 2008; 47, 273-80.

M Toufiq Reza, A Janet, W Bejamin, B Daniela, P Judith, GL Joan and M Jan. Hydrothermal carbonization of biomass for energy and crop production. Bioenerg. Res. 2014; 1, 11-29.

S Nizamuddin, S Shrestha, S Athar, B Si Ali and MA Siddiqui. A critical analysis on palm kernel shell from oil palm industry as a feedstock for solid char production. Rev. Chem. Eng. 2015; 32, 489-505.

SS Jamari and JR Howse. The effect of the hydrothermal carbonization process on palm oil empty fruit bunch. Biomass Bioenerg. 2012; 47, 82-90.

AB Fuertes, MC Arbestain, M Sevilla, JA Macia-Agullo, S Fiol, R Lopez, RJ Smernik, WP Aitkenhead, F Arce and F Macias. Chemical and structural properties of carbonaceous products obtained by pyrolysis and hydrothermal carbonisation of corn stover. Aust. J. Soil Res. 2010; 48, 618-26.

AT Mursito, T Hirajima, K Sasaki, Upgrading and dewatering of raw tropical peat by hydrothermal treatment. Fuel 2010; 89, 635-41.

T Kubilay, K Selhan, B Sema. A review of hydrothermal biomass processing. Renew. Sust. Energ. Rev. 2014; 40, 673-87.

W Lili, G Yupeng, Z Yanchao, L Ying, Q Yuning, R Chunguang, M Xiaoyu and W Zichen. A new route for preparation of hydrochars from rice husk. Biores. Tech. 2010; 101, 9807-10.

W Ru, L Guoqiang, L Min, Z Jianchun and H Xinmin. Preparation and N2, CO2 and H2 adsorption of super activated carbon derived from biomass source hemp (Cannabis sativa L.) steam. Micorpor. Mesopor. Mater. 2012; 158, 108-16.

K Ganesh, S Parshetti, H Kent and B Rajasekhar. Chemical structural and combustion characteristics of carbonaceous products obtained by hydrothermal carbonization of palm empty fruit bunches. Biores. Tech. 2013; 135, 683-9.

LL Wang, YP Guo, B Zou, CG Rong, XY Ma, YN Qu, Y Li and ZC Wang. High surface area porous carbons prepared from hydrochars by phosphoric acid activation. Biores. Tech. 2010; 102, 1947-950.

J Schwan, S Ulrico, V Batori and H Ehrhardt. Raman spectroscopy on amorphous carbon films. J. Appl. Phys. 1996; 80, 440-7.

M Sevilla, AB Fuertes, The production of carbon materials by hydrothermal carbonization of cellulose. Carbon 2009; 47, 2281-9.

M Sevilla, AB Fuertes and R Mokaya. High density hydrogen storage in superactivated carbons from hydrothermally carbonized renewable organic materials. Energ. Environ. Sci. 2011; 4, 1400-10.


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