Enhanced Surface Hardness of Commercially Pure Titanium by Pack Carburization with Rubberwood Charcoal and Rubberwood Ash

Authors

  • Natthaphong KONKHUNTHOT Department of Materials Engineering, Faculty of Engineering and Architecture, Rajamangala University of Technology Isan, Nakhon Ratchasima 30000, Thailand
  • Patcharanut BURANAPIMA Department of Materials Engineering, Faculty of Engineering and Architecture, Rajamangala University of Technology Isan, Nakhon Ratchasima 30000, Thailand
  • Patipan BOONNITEE Department of Materials Engineering, Faculty of Engineering and Architecture, Rajamangala University of Technology Isan, Nakhon Ratchasima 30000, Thailand
  • Mahamasuhaimi MASAE Department of Industrial Engineering, Faculty of Engineering, Rajamangala University of Technology Srivijaya, Songkla 90000, Thailand
  • Peerawas KONGSONG Department of Materials Engineering, Faculty of Engineering and Architecture, Rajamangala University of Technology Isan, Nakhon Ratchasima 30000, Thailand

DOI:

https://doi.org/10.48048/wjst.2021.20632

Keywords:

Pack carburization, Rubberwood charcoal and ash, Surface hardness, CP-Ti, TiC

Abstract

In the present work, pack carburization with rubberwood charcoal and rubberwood ash at 925 °C for 6, 12, and 24 h was carried out to improve the surface hardness of commercially pure titanium (CP-Ti).  X-ray diffraction and energy dispersive spectrometer analyses revealed the formation of titanium carbide (TiC) and the existence of oxygen diffusion in the carburized surface. The surface hardness of most optimized conditions has remarkably increased by 481 % as compared to untreated CP-Ti (from 175 HV to 1016 HV) due to the TiC surface layer, while the hardened oxygen diffusion layer of about 300 μm in-depth, as clearly seen in the microhardness profiles is useful for increased load-bearing capacity. Consequently, pack carburization with rubberwood charcoal and rubberwood ash is a promising surface modification technique, which can significantly enhance the surface hardness and increase the load-bearing capacity of CP-Ti for biomedical and tribological applications.

HIGHLIGHTS

  • Rubberwood charcoal and ash are a new carbon source to fabricate the TiC layer on CP-Ti.
  • Formation of the TiC layer remarkably enhances the surface hardness of CP-Ti by 481 %.
  • The hardened oxygen diffusion layer is beneficial to load-bearing and anti-wear capacity.

GRAPHICAL ABSTRACT

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References

DB Lewis, A Leyland, PR Stevenson, J Cawley and A Matthews. Metallurgical study of low-temperature plasma carbon diffusion treatments for stainless steels. Surf. Coat. Technol. 1993; 60, 416-23.

KT Rie. Recent advances in plasma diffusion processes. Surf. Coat. Technol. 1999; 112, 56-62.

M Egawa, N Ueda, K Nakata, M Tsujikawa and M Tanaka. Effect of additive alloying element on plasma nitriding and carburizing behavior for austenitic stainless steels. Surf. Coat. Technol. 2010; 205, 246-51.

CJ Scheuer, RP Cardoso, FI Zanetti, T Amaral and F Brunatto. Low-temperature plasma carburizing of AISI 420 martensitic stainless steel: Influence of gas mixture and gas flow rate. Surf. Coat. Technol. 2012; 206, 5085-90.

Y Wei, Z Zurecki and RD Sisson. Optimization of processing conditions in plasma activated nitrogen-hydrocarbon carburizing. Surf. Coat. Technol. 2015; 272, 190-7.

N Tsuji, S Tanaka and T Takasugi. Evaluation of surface-modified Ti-6Al-4V alloy by combination of plasma-carburizing and deep-rolling. Mater. Sci. Eng. A 2008; 488, 139-45.

N Tsuji, S Tanaka and T Takasugi. Effects of combined plasma-carburizing and shot peening on fatigue and wear properties of Ti-6Al-4V alloy. Surf. Coat. Technol. 2009; 203, 1400-5.

X Yazhe, J Chaoping and H Jianmin. Surface strengthening of Ti-6Al-4V alloy by grow plasma carbonization process. Rare Metal Mat. Eng. 2013; 42, 1101-4.

Y Kaneno, N Matsumoto, N Tsuji, S Tanaka and T Takasugi. Plasma-assisted surface hardening of dual two-phase intermetallic alloy composed of Ni3X type structures. Mater Sci. Eng. A 2009; 516, 84-9.

H Han, S Baba, H Kitagawa, SA Sulil, K Hasezaki, T Kato, K Arakawa and Y Noda. Plasma-carburization of nickel-based self-fluxing alloy. Vacuum 2005; 78, 27-32.

R Bailey and Y Sun. Pack carburisation of commercially pure titanium with limited oxygen diffusion for improved tribological properties. Surf. Coat. Technol. 2015; 261, 28-34.

R Bailey and Y Sun. Corrosion and tribocorrosion performance of pack-carburized. commercially pure titanium with limited oxygen diffusion in a 0.9 % NaCl solution. J. Bio-Tribo-Corros. 2018; 4, 1-12.

PV Bharathy, D Nataraj, PK Chu, H Wang, Q Yang, MS RN Kiran, JS Albero and D Mangalaraj. Effect of titanium incorporation on the structural, mechanical and biocompatible properties of DLC thin films prepared by reactive-biased target ion beam deposition method. Appl. Surf. Sci. 2010; 257, 143-50.

CM Liu and SY Wu. From biomass waste to biofuels and biomaterial building blocks. Renew Energ. 2016; 96, 1056-62.

AD Adepoju, JA Adebisi, JK Odusote, II Ahmed and SB Hassan. Preparation of Silica from Cassava Periderm. J. Solid Waste Technol. Manag. 2016; 42, 216-21.

VS Aigbodion, SB Hassan and JO Agunsoye. Effect of bagasse ash reinforcement on dry sliding wear behaviour of polymer matrix composites. Mater. Des. 2012; 33, 322-7.

S Gu, J Zhou, Z Luo, Q Wang and Z Shi. Kinetic study on the preparation of silica from rice husk under various pretreatments. J. Therm. Anal. Calorim. 2015; 119, 2159-69.

S Venkateswaran, R Yuvakkumar and V Rajendran. Nano silicon from nano silica using natural resource (Rha) for solar cell fabrication. Phosphorus sulfur Silicon Relat Elem. 2012; 188, 1178-93.

EC Achinivu, RM Howard, G Li, H Graczb and WA Henderson. Lignin extraction from biomass with protic ionic liquids. Green Chem. 2014; 16, 1114-9.

N Thammachot, P Nachaisit, W Homjabok, C Peeratatsuwan, A Mayai and J Nithikarnjanatharn. The effects of energizer and carburizing temperature and time on mechanical properties of hardened big knives in the pack carburizing process. KKU. Eng. J. 2016; 43, 172-7.

M Masae, W Sririkun, P Kongsong and A Jeenarong. Preparation calcium phosphate bioceramic powders from rubber wood ash. Int. J. Innov. Sci. Eng. Technol. 2016; 3, 226-31.

M Masae, L Sikong, P Kongsong, P Phoempoon, S Rawangwong and W Sririkun. Application of rubber wood ash for removal nickel and copper from aqueous solution. Environ Nat. Resour. J. 2013; 11, 17-27.

BJ Choi, IY Kim, YZ Lee and YJ Kim. Microstructure and friction/wear behavior of (TiB + TiC) particulate-reinforced titanium matrix composites. Wear 2014; 318, 68-77.

XY Liu, PK Chu and CX Ding. Surface modification of titanium, titanium alloys, and related materials for biomedical applications. Mater. Sci. Eng. R. 2004; 47, 49-121.

Y Oshida. Bioscience and Bioengineering of Titanium Materials. Elsevier, USA, 2013, p. 9-34.

DC Ghosh and R Biswas. Theoretical Calculation of Absolute Radii of Atoms and Ions. Part 1. The Atomic Radii. Int. J. Mol. Sci. 2002; 3, 87-113.

ZX Zhang, H Dong, T Bell and B Xu. The effect of treatment condition on boost diffusion of thermally oxidised titanium alloy, J. Alloy Compd. 2007; 431, 93-9.

H Dong and XY Li. Oxygen boost diffusion for the deep-case hardening of titanium alloys. Mater. Sci. Eng. A. 2000; 280, 303-10.

F Omidbakhsh, AR Ebrahimi, SH Mousavi, RA Khosroshahi and S Nazarpour. Effect of oxygen boost diffusion treatment on fatigue behavior of Ti-4Al-2V alloy. Surf. Coat. Technol. 2011; 205, 2954-63.

S Kumar, TS Narayanan, SG Raman and SK Seshadri. Evaluation of fretting corrosion behaviour of CP-Ti for orthopaedic implant applications. Tribol. Int. 2010; 43, 1245-52.

M Jamesh, TS NS Narayanan and PK Chu. Thermal oxidation of titanium: Evaluation of corrosion resistance as a function of cooling rate. Mater. Chem. Phys. 2013; 138, 565-72.

AR Shankar, NS Karthiselva and UK Mudali. Thermal oxidation of titanium to improve corrosion resistance in boiling nitric acid medium. Surf. Coat. Technol. 2013; 235, 45-53.

Y Luo, S Ge, H Liu and Z Jin. Microstructure analysis and wear behavior of titanium cermet femoral head with hard TiC layer. J. Biomech. 2009; 42, 2708-11.

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Published

2021-06-28

How to Cite

KONKHUNTHOT, N. ., BURANAPIMA, P. ., BOONNITEE, P. ., MASAE, M. ., & KONGSONG, P. . (2021). Enhanced Surface Hardness of Commercially Pure Titanium by Pack Carburization with Rubberwood Charcoal and Rubberwood Ash. Walailak Journal of Science and Technology (WJST), 18(13), Article 20632 (10 pages). https://doi.org/10.48048/wjst.2021.20632